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HomeMy WebLinkAboutSDS 2451. IDENTIFICATION Product identifier Product Code S245-0245A Product Name ULTRA-TREAD S Other means of identification Common Name SERIES 241/242/245, PART A Recommended use of the chemical and restrictions on use Recommended Use industrial paint. Uses advised against Consumer use, For professional use only. Not for residential use. Details of the supplier of the safety data sheet Emergency telephone number Company Phone Number Tnemec Regulatory Dept: 816-474-3400 24 Hour Emergency Phone Number 800-535-5053 (Infotrac) 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Skin sensitization Category 1 Germ cell mutagenicity Category 1B Carcinogenicity Category 1B Reproductive Toxicity Category 1B Label elements EMERGENCY OVERVIEW ______________________________________________________________________________________________ Page 1 / 8 Revision Number 7 Hazard statements May cause an allergic skin reaction May cause genetic defects May cause cancer May damage fertility or the unborn child Manufacturer Address Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372 816-474-3400 Safety Data Sheet Distributor Tnemec Company, Inc. 86 Boul, des Entreprises, Ste. 203, Boisbriand, Quebec Canada J7G 2T3 Issue Date 10-Jan-2017 Revision Date 10-Jan-2017 Danger ______________________________________________________________________________________________ Precautionary Statements PreventionObtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Avoid breathing dust/fume/gas/mist/vapors/spray Contaminated work clothing should not be allowed out of the workplace Wear protective gloves Response IF exposed or concerned: Get medical advice/attention IF ON SKIN: Wash with plenty of soap and water If skin irritation or rash occurs: Get medical advice/attention Wash contaminated clothing before reuse Storage Store locked up Keep away from children Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Other information Causes mild skin irritation Very toxic to aquatic life with long lasting effects SEE SAFETY DATA SHEET Acute Toxicity 55.7018 % of the mixture consists of ingredient(s) of unknown toxicity. 3. COMPOSITION/INFORMATION ON INGREDIENTS Component CAS-No Weight-% BUTYL BENZYL PHTHALATE 85-68-7 10 - 30% ALKYL GLYCIDYL ETHER 68609-97-2 1 - 10% 1-DODECENE 112-41-4 0.1 - 1% *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures General advice Show this safety data sheet to the doctor in attendance. Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If symptoms persist, call a physician. Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If symptoms persist, call a physician. ______________________________________________________________________________________________ Page 2 / 8 Revision Date 10-Jan-2017S245-0245A ULTRA-TREAD S Odor SlightAppearance opaque Physical state liquid ______________________________________________________________________________________________ Inhalation Remove to fresh air. Oxygen or artificial respiration if needed. Ingestion If swallowed, do not induce vomiting. Get medical attention immediately. Self-protection of the first aider Use personal protective equipment. Avoid contact with eyes, skin and clothing. Most important symptoms and effects, both acute and delayed Notes to physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Water spray. Dry powder. Foam. Carbon dioxide. Unsuitable extinguishing media No information available. Specific hazards arising from the chemical Thermal decomposition can lead to release of irritating gases and vapours In the event of fire and/or explosion do not breathe fumes Hazardous combustion productsHazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide. Unidentified organic and inorganic compounds. Carbon dioxide. Hydrocarbons. Nitrogen oxides (NOx). Protective equipment and precautions for firefighters Use water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away from heat/sparks/open flames/hot surfaces. MAY CAUSE HEAT AND PRESSURE BUILD-UP IN CLOSED CONTAINERS. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Avoid contact with eyes, skin and clothing. Use personal protective equipment. Remove all sources of ignition. Environmental Precautions Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary sewer system. Methods and material for containment and cleaning up Methods for containment Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non-sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminated absorbent, container and unused contents in accordance with local, state and federal regulations. 7. HANDLING AND STORAGE Precautions for safe handling ______________________________________________________________________________________________ Page 3 / 8 S245-0245A ULTRA-TREAD S Revision Date 10-Jan-2017 ______________________________________________________________________________________________ Handling Close container after each use. Avoid contact with eyes, skin and clothing. Do not eat, drink or smoke when using this product. If splashes are likely to occur, wear goggles. Wear protective gloves/clothing. Do not burn, or use a cutting torch on, the empty drum. When used in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling. Conditions for safe storage, including any incompatibilities Storage Keep container tightly closed in a dry and well-ventilated place. Keep out of the reach of children. Incompatible products Strong oxidizing agents. Strong bases. Strong acids. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure guidelines . Appropriate engineering controls Engineering measures Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH''s Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Individual protection measures, such as personal protective equipment Eye/face protection Safety glasses with side-shields Skin and body protection Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Respiratory protection Use only with adequate ventilation. Do not breathe vapors, spray mist, or dust. Ensure fresh air entry during application and drying. If you experience eye watering, headache or dizziness or if air monitoring demonstrates vapor/mist or dust levels are above applicable limits, wear an appropriate, properly fitted respirator (NIOSH/MSHA approved) during and after application. Follow respirator manufacturer's directions for respirator use. General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. Avoid breathing dust created by cutting, sanding, or grinding. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state liquid ______________________________________________________________________________________________ Page 4 / 8 Boiling point / boiling range 100 °C / 212.0 °F Odor threshold No information available Flash point 60 °C / 140 °F Appearance Pensky Martens - Closed Cup opaque Evaporation rate No data available Property Flammability (solid, gas) Values No information available Odor Flammability Limit in Air Remarks No data available Slight Upper flammability limit N/A pH Lower flammability limit N/A S245-0245A ULTRA-TREAD S Vapor pressure No data available No data available Color Melting point / freezing point No information available No data available Revision Date 10-Jan-2017 ______________________________________________________________________________________________ Other Information Density 8.44555 lbs/gal Volatile organic compounds (VOC) content .105 lbs/gal Total volatiles weight percent 29.8870 % Total volatiles volume percent 30.5123 % 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions None under normal processing. Conditions to avoid Heat, flames and sparks. Incompatible materials Strong oxidizing agents, Strong bases, Strong acids Hazardous decomposition products Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide. Unidentified organic and inorganic compounds. Carbon dioxide. Hydrocarbons. Nitrogen oxides (NOx). 11. TOXICOLOGICAL INFORMATION Information on Likely Routes of Exposure Inhalation May cause central nervous system depression with nausea, headache, dizziness, vomiting, and incoordination. Eye contact Irritating to eyes. Skin contact Irritating to skin. Ingestion Harmful if swallowed. Component LD50 Oral LD50 Dermal LC50 Inhalation BUTYL BENZYL PHTHALATE 85-68-7 = 2330 mg/kg ( Rat )= 6700 mg/kg ( Rat )> 6.7 mg/L ( Rat ) 4 h ALKYL GLYCIDYL ETHER 68609-97-2 = 17100 mg/kg ( Rat ) 1-DODECENE 112-41-4 > 10000 mg/kg ( Rat )> 10000 mg/kg ( Rat ) Information on toxicological effects ______________________________________________________________________________________________ Page 5 / 8 Specific gravity 1.01491 Autoignition temperature No data available S245-0245A ULTRA-TREAD S No data available Decomposition temperature g/cm3Vapor density Kinematic viscosity Water solubility No data available Insoluble in cold water Dynamic viscosity 150 centipoises Revision Date 10-Jan-2017 Solubility in other solvents No data available No data available Partition coefficient: n-octanol/water No data available ______________________________________________________________________________________________ Symptoms Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Skin disorders. Delayed and immediate effects as well as chronic effects from short and long-term exposure Chronic Toxicity NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Sensitization May cause sensitization of susceptible persons. Mutagenicity May cause genetic defects. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Component ACGIH IARC NTP OSHA BUTYL BENZYL PHTHALATE 85-68-7 Group 3 Reproductive effects May damage fertility or the unborn child. Developmental effects Developmental effects. STOT - single exposure No information available STOT - repeated exposure No information available Aspiration hazard Based on product level data, this product does not meet the requirement to be classified as an aspiration hazard. However, this product contains an ingredient that may cause aspiration if swallowed. Acute Toxicity 55.7018 % of the mixture consists of ingredient(s) of unknown toxicity. 12. ECOLOGICAL INFORMATION Ecotoxicity Very toxic to aquatic life with long lasting effects 58.2874 % of the mixture consists of components(s) of unknown hazards to the aquatic environment Component Toxicity to algae Toxicity to fish Toxicity to daphnia BUTYL BENZYL PHTHALATE 85-68-7 0.02 - 0.25: 96 h Pseudokirchneriella subcapitata mg/L EC50 0.2 - 28.2: 72 h Pseudokirchneriella subcapitata mg/L EC50 1.0 - 10.0: 96 h Lepomis macrochirus mg/L LC50 static 1.0 - 10.0: 96 h Oncorhynchus mykiss mg/L LC50 static 1.39 - 3.88: 96 h Pimephales promelas mg/L LC50 flow-through 0.82: 96 h Oncorhynchus mykiss mg/L LC50 flow-through 0.78: 96 h Pimephales promelas mg/L LC50 static 1.28: 48 h Daphnia magna mg/L EC50 semi-static 0.76: 48 h Daphnia magna mg/L EC50 Flow through 0.97: 48 h Daphnia magna mg/L EC50 0.9 - 1.1: 48 h Daphnia magna mg/L EC50 Static Persistence and degradability No information available. Bioaccumulation No information available. Mobility in Environmental Media Component log Pow BUTYL BENZYL PHTHALATE 85-68-7 3.57 - 4.91 Other Adverse Effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal Methods Keep container tightly closed. If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminated absorbent, container and unused contents in accordance with local, state and federal regulations.______________________________________________________________________________________________ Page 6 / 8 S245-0245A ULTRA-TREAD S Revision Date 10-Jan-2017 ______________________________________________________________________________________________ Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Component RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes BUTYL BENZYL PHTHALATE 85-68-7 Included in waste stream: F039 14. TRANSPORT INFORMATION DOT Proper Shipping Name paint,water base freezable Not regulated IATA UN/ID no.1263 Proper Shipping Name paint Hazard Class 3 Packing Group III ERG Code 366 Additional information Call TNEMEC Traffic Department - 816-474-3400 for additional information or other modes of Transportation. 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Does not comply ENCS Does not comply IECSC Complies KECL Does not comply PICCS Does not comply AICS Complies TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances United States of America SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and and Title 40n of the Code of Federal Regulations, Part 372. SARA 311/312 Hazardous Categorization Acute Health Hazard Yes Chronic Health Hazard Yes Fire Hazard No Sudden Release of Pressure Hazard No ______________________________________________________________________________________________ Page 7 / 8 S245-0245A ULTRA-TREAD S Revision Date 10-Jan-2017 ______________________________________________________________________________________________ Reactive Hazard No Component CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances BUTYL BENZYL PHTHALATE 85-68-7 X X CERCLA Component Hazardous Substances RQs CERCLA EHS RQs RQ BUTYL BENZYL PHTHALATE 85-68-7 100 lb RQ 100 lb final RQ RQ 45.4 kg final RQ United States of America California Prop. 65 WARNING! This product contains a chemical known in the State of California to cause cancer Component California Prop. 65 BUTYL BENZYL PHTHALATE - 85-68-7 Developmental California SCAQMD Rule 443 Contains Photochemically Reactive Solvent State Right-to-Know Component New Jersey Massachusetts Pennsylvania BUTYL BENZYL PHTHALATE 85-68-7 X X X 16. OTHER INFORMATION Prepared By Tnemec Regulatory Dept: 816-474-3400 Revision Date 10-Jan-2017 Revision Summary 9 4 5 7 10 11 14 15 1 Disclaimer For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. End of SDS ______________________________________________________________________________________________ Page 8 / 8 Instability 1 Physical hazard * S245-0245A ULTRA-TREAD S HMIS (Hazardous Material Information System) NFPA Health 2*Flammability 1 Revision Date 10-Jan-2017 Reactivity 1 Health 2 Flammability 1 1. IDENTIFICATION Product identifier Product Code S245-0245B Product Name ULTRA-TREAD S CONVERTER Other means of identification Common Name SERIES 241/242/245, PART B Recommended use of the chemical and restrictions on use Recommended Use industrial paint. Uses advised against Consumer use, For professional use only. Not for residential use. Details of the supplier of the safety data sheet Emergency telephone number Company Phone Number Tnemec Regulatory Dept: 816-474-3400 24 Hour Emergency Phone Number 800-535-5053 (Infotrac) 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Acute toxicity - Inhalation (Vapors)Category 4 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2B Respiratory sensitization Category 1 Skin sensitization Category 1 Specific target organ toxicity (single exposure)Category 3 Specific target organ toxicity (repeated exposure)Category 1 Label elements EMERGENCY OVERVIEW ______________________________________________________________________________________________ Page 1 / 8 Danger Distributor Tnemec Company, Inc. 86 Boul, des Entreprises, Ste. 203, Boisbriand, Quebec Canada J7G 2T3 Issue Date 09-Feb-2017 Hazard statements Harmful if inhaled Causes skin irritation Causes eye irritation May cause allergy or asthma symptoms or breathing difficulties if inhaled May cause an allergic skin reaction May cause respiratory irritation Causes damage to organs through prolonged or repeated exposure Revision Date 09-Feb-2017 Revision Number 10 Manufacturer Address Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372 816-474-3400 Safety Data Sheet ______________________________________________________________________________________________ Precautionary Statements Prevention Use only outdoors or in a well-ventilated area Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection In case of inadequate ventilation wear respiratory protection Contaminated work clothing should not be allowed out of the workplace Do not breathe dust/fume/gas/mist/vapors/spray Do not eat, drink or smoke when using this product ResponseGet medical advice/attention if you feel unwell IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN: Wash with plenty of soap and water Take off contaminated clothing and wash before reuse If skin irritation or rash occurs: Get medical advice/attention IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician Storage Store in a well-ventilated place. Keep container tightly closed Store locked up Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Other information SEE SAFETY DATA SHEET Acute Toxicity 0 % of the mixture consists of ingredient(s) of unknown toxicity. 3. COMPOSITION/INFORMATION ON INGREDIENTS Component CAS-No Weight-% DIPHENYLMETHANE DIISOCYANATE (MDI) POLYMER 9016-87-9 30 - 60% DIPHENYLMETHANE DIISOCYANATE (VOLATILE MONOMER) 101-68-8 30 - 60% DIPHENYLMETHANE DIISOCYANATE (MDI) POLYMER 5873-54-1 10 - 30% 2,2'-DIPHENYLMETHANE DIISOCYANATE 2536-05-2 1 - 10% *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES ______________________________________________________________________________________________ Page 2 / 8 S245-0245B ULTRA-TREAD S CONVERTER Revision Date 09-Feb-2017 Odor SlightAppearance clear Physical state liquid ______________________________________________________________________________________________ Description of first aid measures General advice Show this safety data sheet to the doctor in attendance. Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If symptoms persist, call a physician. Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If symptoms persist, call a physician. Inhalation Remove to fresh air. Oxygen or artificial respiration if needed. Ingestion If swallowed, do not induce vomiting. Get medical attention immediately. Self-protection of the first aider Avoid breathing vapors or mists. Most important symptoms and effects, both acute and delayed Notes to physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing mediaCarbon dioxide. Dry chemical. Dry powder. Unsuitable extinguishing media Water. Specific hazards arising from the chemical Thermal decomposition can lead to release of irritating gases and vapours In the event of fire and/or explosion do not breathe fumes Hazardous combustion productsHazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide. Unidentified organic and inorganic compounds. Carbon dioxide. Hydrocarbons. Nitrogen oxides (NOx). Isocyanates. Protective equipment and precautions for firefighters Use water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away from heat/sparks/open flames/hot surfaces. MAY CAUSE HEAT AND PRESSURE BUILD-UP IN CLOSED CONTAINERS. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Avoid contact with eyes, skin and clothing. Use personal protective equipment. Remove all sources of ignition. Ensure adequate ventilation. Environmental Precautions Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary sewer system. Methods and material for containment and cleaning up Methods for containment Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non-sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminated absorbent, container and unused contents in accordance with local, state and federal regulations. ______________________________________________________________________________________________ Page 3 / 8 S245-0245B ULTRA-TREAD S CONVERTER Revision Date 09-Feb-2017 ______________________________________________________________________________________________ 7. HANDLING AND STORAGE Precautions for safe handling Handling Use only with adequate ventilation.Avoid contact with eyes, skin and clothing. Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Do not eat, drink or smoke when using this product. When used in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling. Conditions for safe storage, including any incompatibilities Storage Keep container tightly closed in a dry and well-ventilated place. Keep out of the reach of children. Incompatible products Water. Amines. Strong bases. Alcohols. copper. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure guidelines . Component ACGIH TLV OSHA PEL NIOSH IDLH DIPHENYLMETHANE DIISOCYANATE (VOLATILE MONOMER) 101-68-8 TWA: 0.005 ppm Ceiling: 0.02 ppm Ceiling: 0.2 mg/m3 75 mg/m3 NIOSH IDLH: Immediately Dangerous to Life or Health Appropriate engineering controls Engineering measures Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH''s Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Individual protection measures, such as personal protective equipment Eye/face protection Use chemical resistant splash type goggles. If splashes are likely to occur, wear face-shield. Skin and body protection Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Respiratory protection Use only with adequate ventilation. Do not breathe vapors, spray mist, or dust. Ensure fresh air entry during application and drying. If you experience eye watering, headache or dizziness or if air monitoring demonstrates vapor/mist or dust levels are above applicable limits, wear an appropriate, properly fitted respirator (NIOSH/MSHA approved) during and after application. Follow respirator manufacturer's directions for respirator use. General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. Avoid breathing dust created by cutting, sanding, or grinding. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state liquid ______________________________________________________________________________________________ Page 4 / 8 Color No information available Odor threshold No information available Appearance clear S245-0245B ULTRA-TREAD S CONVERTER Odor Slight Revision Date 09-Feb-2017 ______________________________________________________________________________________________ Other Information Density 10.3293 lbs/gal Volatile organic compounds (VOC) content 0 lbs/gal Total volatiles weight percent 0 % Total volatiles volume percent 0 % 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions None under normal processing. Conditions to avoidHeat, flames and sparks. Incompatible materials Water, Amines, Strong bases, Alcohols, copper Hazardous decomposition products Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide. Unidentified organic and inorganic compounds. Carbon dioxide. Hydrocarbons. Nitrogen oxides (NOx). Isocyanates. 11. TOXICOLOGICAL INFORMATION Information on Likely Routes of Exposure Inhalation Contains isocyanate monomer. If subject to spray application, engineering and administrative controls must be instituted to maintain an exposure level below .005ppm. If these controls are not adequate, the use of an air-supplied respirator is mandatory. May cause sensitization of susceptible persons. Eye contact Severely irritating to eyes. ______________________________________________________________________________________________ Page 5 / 8 No data available Decomposition temperature No data available No data available Kinematic viscosity Flammability (solid, gas) No data available Dynamic viscosity 145 mPa s No data available No data available No information available Property Flammability Limit in Air Melting point / freezing point No data available Upper flammability limit N/A Values No data available Lower flammability limit N/A No data available S245-0245B ULTRA-TREAD S CONVERTER Vapor pressure Boiling point / boiling range 72 °C / 162 °F No data available Vapor density Remarks No data available Specific gravity 1.23853 g/cm3 Flash point Water solubility Insoluble in cold water No information available Revision Date 09-Feb-2017 Solubility in other solvents No data available pH Partition coefficient: n-octanol/water No data available Evaporation rate Autoignition temperature ______________________________________________________________________________________________ Skin contact Irritating to skin. May cause sensitization of susceptible persons. Ingestion Harmful if swallowed. Component LD50 Oral LD50 Dermal LC50 Inhalation DIPHENYLMETHANE DIISOCYANATE (MDI) POLYMER 9016-87-9 = 49 g/kg ( Rat )> 9.4 g/kg ( Rabbit ) > 9400 mg/kg ( Rabbit ) = 490 mg/m3 ( Rat ) 4 h DIPHENYLMETHANE DIISOCYANATE (VOLATILE MONOMER) 101-68-8 = 31600 mg/kg ( Rat ) = 9200 mg/kg ( Rat ) = 369 mg/m3 ( Rat ) 4 h Information on toxicological effects Symptoms Respiratory disorders. Skin disorders. Delayed and immediate effects as well as chronic effects from short and long-term exposure Chronic Toxicity Avoid repeated exposure. Contains isocyanates. May produce an allergic reaction. Sensitization May cause sensitization of susceptible persons. Mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Component ACGIH IARC NTP OSHA DIPHENYLMETHANE DIISOCYANATE (MDI) POLYMER 9016-87-9 Group 3 DIPHENYLMETHANE DIISOCYANATE (VOLATILE MONOMER) 101-68-8 Group 3 Reproductive effects No information available. STOT - single exposure Eyes, Skin, Respiratory system STOT - repeated exposure Causes damage to organs through prolonged or repeated exposure Target organ effects Eyes, respiratory system. Aspiration hazard Based on product level data, this product does not meet the requirement to be classified as an aspiration hazard. However, this product contains an ingredient that may cause aspiration if swallowed. Acute Toxicity 0 % of the mixture consists of ingredient(s) of unknown toxicity. The following values are calculated based on chapter 3.1 of the GHS document . 12. ECOLOGICAL INFORMATION Ecotoxicity 48 % of the mixture consists of components(s) of unknown hazards to the aquatic environment Persistence and degradability No information available. Bioaccumulation No information available. Mobility in Environmental Media Other Adverse Effects No information available 13. DISPOSAL CONSIDERATIONS ______________________________________________________________________________________________ Page 6 / 8 S245-0245B ULTRA-TREAD S CONVERTER Revision Date 09-Feb-2017 ______________________________________________________________________________________________ Waste treatment methods Disposal Methods Keep container tightly closed. If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminated absorbent, container and unused contents in accordance with local, state and federal regulations. Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. 14. TRANSPORT INFORMATION DOT Proper Shipping Name PAINT & RELATED MATERIAL IATA Additional information Call TNEMEC Traffic Department - 816-474-3400 for additional information or other modes of Transportation. 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Does not comply ENCS Complies IECSC Complies KECL Complies PICCS Complies AICS Complies TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61): Component HAPS Data DIPHENYLMETHANE DIISOCYANATE (VOLATILE MONOMER) United States of America SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and and Title 40n of the Code of Federal Regulations, Part 372: Component SARA 313 - Threshold Values DIPHENYLMETHANE DIISOCYANATE (MDI) POLYMER - 9016-87-9 1.0 DIPHENYLMETHANE DIISOCYANATE (VOLATILE MONOMER) - 101-68-8 1.0 DIPHENYLMETHANE DIISOCYANATE (MDI) POLYMER - 5873-54-1 1.0 2,2'-DIPHENYLMETHANE DIISOCYANATE - 2536-05-2 1.0 ______________________________________________________________________________________________ Page 7 / 8 Revision Date 09-Feb-2017S245-0245B ULTRA-TREAD S CONVERTER ______________________________________________________________________________________________ SARA 311/312 Hazardous Categorization Acute Health Hazard Yes Chronic Health Hazard Yes Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No CERCLA Component Hazardous Substances RQs CERCLA EHS RQs RQ DIPHENYLMETHANE DIISOCYANATE (VOLATILE MONOMER) 101-68-8 5000 lb RQ 5000 lb final RQ RQ 2270 kg final RQ United States of America California Prop. 65 WARNING! This product contains a chemical known in the State of California to cause cancer California SCAQMD Rule 443 Contains Photochemically Reactive Solvent State Right-to-Know Component New Jersey Massachusetts Pennsylvania DIPHENYLMETHANE DIISOCYANATE (MDI) POLYMER 9016-87-9 X DIPHENYLMETHANE DIISOCYANATE (VOLATILE MONOMER) 101-68-8 X X X DIPHENYLMETHANE DIISOCYANATE (MDI) POLYMER 5873-54-1 X 2,2'-DIPHENYLMETHANE DIISOCYANATE 2536-05-2 X 16. OTHER INFORMATION Prepared By Tnemec Regulatory Dept: 816-474-3400 Revision Date 09-Feb-2017 Revision Summary 9 4 5 6 7 10 8 11 14 1 Disclaimer For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. End of SDS ______________________________________________________________________________________________ Page 8 / 8 S245-0245B ULTRA-TREAD S CONVERTER Instability 1 Physical hazard * Revision Date 09-Feb-2017 HMIS (Hazardous Material Information System) NFPA Health 3*Flammability 1 Reactivity 1 Health 3 Flammability 1 Safety Data Sheet Issue Date No data available Revision Date 13-Feb-2015 Revision Number 4 1. IDENTIFICATION Product identifier Product Code S245-0245C Product Name ULTRA-TREAD S THERMA TREAD SLU Other means of identification Common Name SERIES 245 PART C Recommended use of the chemical and restrictions on use Recommended Use industrial paint. Uses advised against Consumer use, For professional use only. Not for residential use. Details of the supplier of the safety data sheet Emergency telephone number Company Phone Number Tnemec Regulatory Dept: 816-474-3400 24 Hour Emergency Phone Number 800-535-5053 (Infotrac) 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Acute toxicity - Oral Category 4 Acute toxicity - Inhalation (Dusts/Mists)Category 4 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 1 Skin sensitization Category 1 Carcinogenicity Category 1A Specific target organ toxicity (single exposure)Category 3 Specific target organ toxicity (repeated exposure)Category 1 Label elements EMERGENCY OVERVIEW ______________________________________________________________________________________________ Manufacturer Address Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372 Danger Page 1 / 9 Hazard statements Harmful if swallowed Harmful if inhaled Causes skin irritation Causes serious eye damage May cause an allergic skin reaction May cause cancer May cause respiratory irritation Causes damage to organs through prolonged or repeated exposure ______________________________________________________________________________________________ S245-0245C ULTRA-TREAD S THERMA TREAD SLU Revision Date 13-Feb-2015 Precautionary Statements Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Use only outdoors or in a well-ventilated area Contaminated work clothing should not be allowed out of the workplace Wear protective gloves Do not breathe dust/fume/gas/mist/vapors/spray Response IF exposed or concerned: Get medical advice/attention IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor/physician IF ON SKIN: Wash with plenty of soap and water Take off contaminated clothing and wash before reuse If skin irritation or rash occurs: Get medical advice/attention IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Rinse mouth Storage Store locked up Store in a well-ventilated place. Keep container tightly closed Keep away from children Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Other information Harmful to aquatic life with long lasting effects Cancer hazard. Contains crystalline silica which can cause cancer. (Risk of cancer depends on duration and level of exposure). Respirable crystalline silica (quartz) can cause silicosis, a fibrosis (scarring) of the lungs Exposure of sufficient duration to wet cement, or to dry cement on moist areas of the body, can cause serious, potentially irreversible tissue (skin, eye, respiratory tract) damage due to chemical (caustic) burns, including third degree burns SEE SAFETY DATA SHEET Acute Toxicity 46.7618 % of the mixture consists of ingredient(s) of unknown toxicity. 3. COMPOSITION/INFORMATION ON INGREDIENTS Component CAS-No Weight-% CRYSTALLINE SILICA (QUARTZ)14808-60-7 30 - 60% ALUMINUM SILICATE (TOTAL DUST)1302-93-8 10 - 30% CALCIUM SILICATES AND ALUMINATES 65997-15-1 10 - 30% CRYSALLINE SILICA (CRISTOBALITE)14464-46-1 1 - 10% ______________________________________________________________________________________________ Appearance opaque Page 2 / 9 Physical state powder Odor odorless ______________________________________________________________________________________________ S245-0245C ULTRA-TREAD S THERMA TREAD SLU Revision Date 13-Feb-2015 CALCIUM HYDROXIDE 1305-62-0 1 - 10% AMORPHOUS SILICA 7631-86-9 1 - 10% IRON OXIDE FUME 1309-37-1 1 - 10% GYPSUM 13397-24-5 1 - 10% CRYSTALLINE SILICA (QUARTZ)14808-60-7 0.1 - 1% *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures General advice Show this safety data sheet to the doctor in attendance. Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If symptoms persist, call a physician. Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If symptoms persist, call a physician. Inhalation Remove to fresh air. Oxygen or artificial respiration if needed. Ingestion If swallowed, do not induce vomiting. Get medical attention immediately. Self-protection of the first aider Use personal protective equipment. Avoid contact with eyes, skin and clothing. Most important symptoms and effects, both acute and delayed Notes to physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2). Dry powder. Dry chemical. Foam. Unsuitable extinguishing media No information available. Specific hazards arising from the chemical Thermal decomposition can lead to release of irritating gases and vapours In the event of fire and/or explosion do not breathe fumes Hazardous combustion productsHazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide. Unidentified organic and inorganic compounds. Carbon dioxide (CO2). Hydrocarbons. Nitrogen oxides (NOx). Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions ______________________________________________________________________________________________ Avoid contact with eyes, skin and clothing. Use personal protective equipment. Remove all sources of ignition. Environmental Precautions Page 3 / 9 Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary sewer system. ______________________________________________________________________________________________ S245-0245C ULTRA-TREAD S THERMA TREAD SLU Revision Date 13-Feb-2015 Methods and material for containment and cleaning up Methods for containment Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non-sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. Methods for cleaning up Shovel or sweep up. 7. HANDLING AND STORAGE Precautions for safe handling Handling Close container after each use. Avoid contact with eyes, skin and clothing. Do not eat, drink or smoke when using this product. Tightly fitting safety goggles. Wear protective gloves/clothing. When used in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling. Conditions for safe storage, including any incompatibilities Storage Keep container tightly closed in a dry and well-ventilated place. Keep out of the reach of children. Incompatible products Acids. Ammonia. Aluminum. Oxides of phosphorous. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure guidelines . Component ACGIH TLV OSHA PEL NIOSH IDLH CRYSTALLINE SILICA (QUARTZ) 14808-60-7 TWA: 0.025 mg/m3 TWA: 0.1 mg/m3 50 mg/m3 ALUMINUM SILICATE (TOTAL DUST) 1302-93-8 TWA: 1 mg/m3 - CALCIUM SILICATES AND ALUMINATES 65997-15-1 TWA: 1 mg/m3 TWA: 10 mg/m3 TWA: 5 mg/m3 TWA: 15 mg/m3 5000 mg/m3 CRYSALLINE SILICA (CRISTOBALITE) 14464-46-1 TWA: 0.025 mg/m3 TWA: 0.05 mg/m3 25 mg/m3 CALCIUM HYDROXIDE 1305-62-0 TWA: 5 mg/m3 TWA: 5 mg/m3 TWA: 15 mg/m3 AMORPHOUS SILICA 7631-86-9 -TWA: 6 mg/m3 3000 mg/m3 IRON OXIDE FUME 1309-37-1 TWA: 5 mg/m3 TWA: 10 mg/m3 TWA: 5 mg/m3 TWA: 15 mg/m3 2500 mg/m3 GYPSUM 13397-24-5 TWA: 10 mg/m3 TWA: 15 mg/m3 TWA: 5 mg/m3 CRYSTALLINE SILICA (QUARTZ) 14808-60-7 ______________________________________________________________________________________________ TWA: 0.025 mg/m3 TWA: 0.1 mg/m3 50 mg/m3 NIOSH IDLH: Immediately Dangerous to Life or Health Page 4 / 9 Appropriate engineering controls ______________________________________________________________________________________________ S245-0245C ULTRA-TREAD S THERMA TREAD SLU Revision Date 13-Feb-2015 Engineering measures Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH''s Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Individual protection measures, such as personal protective equipment Eye/face protection Use chemical resistant splash type goggles. If splashes are likely to occur, wear face-shield. Skin and body protection Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Respiratory protection Use only with adequate ventilation. Do not breathe vapors, spray mist, or dust. Ensure fresh air entry during application and drying. If you experience eye watering, headache or dizziness or if air monitoring demonstrates vapor/mist or dust levels are above applicable limits, wear an appropriate, properly fitted respirator (NIOSH/MSHA approved) during and after application. Follow respirator manufacturer's directions for respirator use. General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. Avoid breathing dust created by cutting, sanding, or grinding. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state powder Other Information Density 22.60796 lbs/gal Volatile organic compounds (VOC) content .000 lbs/gal Total volatiles weight percent .0000 % Total volatiles volume percent .0000 % 10. STABILITY AND REACTIVITY Appearance opaque Odor odorless Color No information available Odor threshold No information available Property Values Remarks pH No data available Melting point / freezing point No data available Boiling point / boiling range No information available Flash point No information available Evaporation rate No data available Flammability (solid, gas)No information available Flammability Limit in Air No data available Upper flammability limit N/A Lower flammability limit N/A Vapor pressure No data available Vapor density No data available Specific gravity 2.71681 g/cm3 Water solubility Insoluble in cold water Solubility in other solvents No data available Partition coefficient: n-octanol/water No data available Autoignition temperature No data available Decomposition temperature No data available ______________________________________________________________________________________________ Kinematic viscosity No data available Dynamic viscosity Page 5 / 9 No data available ______________________________________________________________________________________________ S245-0245C ULTRA-TREAD S THERMA TREAD SLU Revision Date 13-Feb-2015 Reactivity Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions None under normal processing. Conditions to avoid Heat, flames and sparks. Incompatible materials Acids, Ammonia, Aluminum, Oxides of phosphorous Hazardous decomposition productsHazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide. Unidentified organic and inorganic compounds. Carbon dioxide (CO2). Hydrocarbons. Nitrogen oxides (NOx). 11. TOXICOLOGICAL INFORMATION Information on Likely Routes of Exposure Inhalation May cause central nervous system depression with nausea, headache, dizziness, vomiting, and incoordination. Eye contact Severely irritating to eyes. May cause irreversible damage to eyes. Skin contact Contact causes severe skin irritation and possible burns. Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. Ingestion Harmful if swallowed. Component LD50 Oral LD50 Dermal LC50 Inhalation CRYSTALLINE SILICA (QUARTZ) 14808-60-7 = 500 mg/kg ( Rat ) CALCIUM HYDROXIDE 1305-62-0 = 7340 mg/kg ( Rat ) AMORPHOUS SILICA 7631-86-9 > 5000 mg/kg ( Rat )> 2000 mg/kg ( Rabbit )> 2.2 mg/L ( Rat ) 1 h IRON OXIDE FUME 1309-37-1 > 10000 mg/kg ( Rat ) CRYSTALLINE SILICA (QUARTZ) 14808-60-7 = 500 mg/kg ( Rat ) Information on toxicological effects Symptoms Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Skin disorders. Delayed and immediate effects as well as chronic effects from short and long-term exposure Chronic Toxicity Cancer hazard. Contains crystalline silica which can cause cancer. (Risk of cancer depends on duration and level of exposure). Sensitization May cause sensitization of susceptible persons. Mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Component ACGIH IARC NTP OSHA ______________________________________________________________________________________________ CRYSTALLINE SILICA (QUARTZ) 14808-60-7 A2 Group 1 Known Page 6 / 9 X No data available ______________________________________________________________________________________________ S245-0245C ULTRA-TREAD S THERMA TREAD SLU Revision Date 13-Feb-2015 CRYSALLINE SILICA (CRISTOBALITE) 14464-46-1 A2 Group 1 X AMORPHOUS SILICA 7631-86-9 Group 3 IRON OXIDE FUME 1309-37-1 Group 3 CRYSTALLINE SILICA (QUARTZ) 14808-60-7 A2 Group 1 Known X Reproductive effects No information available. STOT - single exposure Skin, Eyes, Lungs STOT - repeated exposure Causes damage to organs through prolonged or repeated exposure Target organ effects Eyes, respiratory system, Skin, Lungs. Aspiration hazard No information available. Acute Toxicity 46.7618 % of the mixture consists of ingredient(s) of unknown toxicity. 12. ECOLOGICAL INFORMATION Ecotoxicity Harmful to aquatic life with long lasting effects 77.9221 % of the mixture consists of components(s) of unknown hazards to the aquatic environment Component Toxicity to algae Toxicity to fish Toxicity to daphnia CALCIUM HYDROXIDE 1305-62-0 160: 96 h Gambusia affinis mg/L LC50 static AMORPHOUS SILICA 7631-86-9 440: 72 h Pseudokirchneriella subcapitata mg/L EC50 5000: 96 h Brachydanio rerio mg/L LC50 static 7600: 48 h Ceriodaphnia dubia mg/L EC50 Persistence and degradability No information available. Bioaccumulation No information available. Mobility in Environmental Media Other Adverse Effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal Methods Keep container tightly closed. If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminated absorbent, container and unused contents in accordance with local, state and federal regulations. Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. California Hazardous Waste Status This product contains one or more substances that are listed with the State of California as a hazardous waste ______________________________________________________________________________________________ Component CAWAST CALCIUM SILICATES AND ALUMINATES 65997-15-1 Special Page 7 / 9 CALCIUM HYDROXIDE 1305-62-0 Corrosive ______________________________________________________________________________________________ S245-0245C ULTRA-TREAD S THERMA TREAD SLU Revision Date 13-Feb-2015 14. TRANSPORT INFORMATION DOT Proper Shipping Name SILICA, N.O.I.-20-P.C.F., GREATER (ITEM 176370, SUB 3) IATA Proper Shipping Name Not regulated Additional information Call TNEMEC Traffic Department - 816-474-3400 for additional information or other modes of Transportation. 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Does not comply ENCS Does not comply IECSC Complies KECL Does not comply PICCS Does not comply AICS Does not comply TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances United States of America SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and and Title 40n of the Code of Federal Regulations, Part 372. SARA 311/312 Hazardous Categorization Acute Health Hazard Yes Chronic Health Hazard Yes Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No CERCLA United States of America California Prop. 65 WARNING! This product contains a chemical known in the State of California to cause cancer ______________________________________________________________________________________________ Component California Prop. 65 CRYSTALLINE SILICA (QUARTZ) - 14808-60-7 Carcinogen Page 8 / 9 CRYSTALLINE SILICA (QUARTZ) - 14808-60-7 Carcinogen ______________________________________________________________________________________________ S245-0245C ULTRA-TREAD S THERMA TREAD SLU Revision Date 13-Feb-2015 California SCAQMD Rule 443 Does Not Contain Photochemically Reactive Solvent State Right-to-Know Component New Jersey Massachusetts Pennsylvania CRYSTALLINE SILICA (QUARTZ) 14808-60-7 X X X CALCIUM SILICATES AND ALUMINATES 65997-15-1 X X X CRYSALLINE SILICA (CRISTOBALITE) 14464-46-1 X X X CALCIUM HYDROXIDE 1305-62-0 X X X AMORPHOUS SILICA 7631-86-9 X X X IRON OXIDE FUME 1309-37-1 X X X GYPSUM 13397-24-5 X X CRYSTALLINE SILICA (QUARTZ) 14808-60-7 X X X 16. OTHER INFORMATION Prepared By Tnemec Regulatory Dept: 816-474-3400 Revision Date 13-Feb-2015 Revision Summary 9 4 5 7 10 8 11 14 15 Disclaimer For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. End of MSDS NFPA Health 2 Flammability 1 Instability 0 ______________________________________________________________________________________________ Physical hazard * HMIS (Hazardous Material Information System) Health 2*Flammability 1 Page 9 / 9 Reactivity 0 1. IDENTIFICATION Product identifier Product Code S244-00BGD Product Name ULTRA-TREAD BEIGE Other means of identification Common Name SERIES 243/244/245, PART D Recommended use of the chemical and restrictions on use Recommended Use industrial paint. Uses advised against Consumer use, For professional use only. Not for residential use. Details of the supplier of the safety data sheet Emergency telephone number Company Phone Number Tnemec Regulatory Dept: 816-474-3400 24 Hour Emergency Phone Number 800-535-5053 (Infotrac) 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Acute toxicity - Oral Category 4 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2B Carcinogenicity Category 2 Specific target organ toxicity (single exposure)Category 3 Label elements EMERGENCY OVERVIEW Precautionary Statements ______________________________________________________________________________________________ Page 1 / 9 Hazard statements Harmful if swallowed Causes skin irritation Causes eye irritation Suspected of causing cancer May cause respiratory irritation. May cause drowsiness or dizziness Distributor Tnemec Company, Inc. 86 Boul, des Entreprises, Ste. 203 Boisbriand, Quebec Canada J7G 2T3 Safety Data Sheet Issue Date 30-Nov-2015 Revision Date 30-Nov-2015 WARNING Revision Number 7 Manufacturer Address Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372 Appearance opaque Physical state No information available Odor No information available ______________________________________________________________________________________________ PreventionObtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Response IF exposed or concerned: Get medical advice/attention IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention IF ON SKIN: Wash with plenty of soap and water If skin irritation occurs: Get medical advice/attention Take off contaminated clothing and wash before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Storage Keep away from children Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Other information Harmful to aquatic life with long lasting effects SEE SAFETY DATA SHEET 3. COMPOSITION/INFORMATION ON INGREDIENTS Component CAS-No Weight-% IRON OXIDE FUME 1309-37-1 60 - 100% COBALT ALUMINATE BLUE SPINEL 1345-16-0 60 - 100% CHROMIC (III) OXIDE 1308-38-9 60 - 100% TITANIUM DIOXIDE (TOTAL DUST)13463-67-7 60 - 100% TITANIUM DIOXIDE (TOTAL DUST)13463-67-7 60 - 100% IRON OXIDE FUME 1309-37-1 1 - 10% AMORPHOUS SILICA 7631-86-9 1 - 10% *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures General advice If symptoms persist, call a physician. Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If symptoms persist, call a physician. Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If symptoms persist, call a physician. Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately. Ingestion If swallowed, do not induce vomiting. Get medical attention immediately. ______________________________________________________________________________________________ Page 2 / 9 Revision Date 30-Nov-2015S244-00BGD ULTRA-TREAD BEIGE ______________________________________________________________________________________________ Self-protection of the first aider Use personal protective equipment. Avoid contact with eyes, skin and clothing. Most important symptoms and effects, both acute and delayed Notes to physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable extinguishing media No information available. Specific hazards arising from the chemical No information available Hazardous combustion productsHazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide. Unidentified organic and inorganic compounds. Carbon dioxide. Hydrocarbons. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation. Avoid contact with skin and eyes. Use personal protective equipment. Environmental Precautions Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary sewer system. Methods and material for containment and cleaning up Methods for containment Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non-sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. Methods for cleaning up Pick up and transfer to properly labelled containers. 7. HANDLING AND STORAGE Precautions for safe handling Handling Wear personal protective equipment. Avoid contact with eyes, skin and clothing. Remove and wash contaminated clothing before re-use. Keep away from open flames, hot surfaces and sources of ignition. Do not breathe vapours/dust. Ensure adequate ventilation. Do not ingest. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Conditions for safe storage, including any incompatibilities Storage Keep container tightly closed in a dry and well-ventilated place. Keep out of the reach of children. Incompatible products Metals. Aluminum. Zinc. calcium. ______________________________________________________________________________________________ Page 3 / 9 S244-00BGD ULTRA-TREAD BEIGE Revision Date 30-Nov-2015 ______________________________________________________________________________________________ 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure guidelines . Component ACGIH TLV OSHA PEL NIOSH IDLH IRON OXIDE FUME 1309-37-1 TWA: 5 mg/m3 TWA: 10 mg/m3 TWA: 5 mg/m3 TWA: 15 mg/m3 2500 mg/m3 COBALT ALUMINATE BLUE SPINEL 1345-16-0 TWA: 0.02 mg/m3 TWA: 1 mg/m3 - CHROMIC (III) OXIDE 1308-38-9 TWA: 0.5 mg/m3 -25 mg/m3 TITANIUM DIOXIDE (TOTAL DUST) 13463-67-7 TWA: 10 mg/m3 TWA: 10 mg/m3 TWA: 15 mg/m3 5000 mg/m3 TITANIUM DIOXIDE (TOTAL DUST) 13463-67-7 TWA: 10 mg/m3 TWA: 10 mg/m3 TWA: 15 mg/m3 5000 mg/m3 IRON OXIDE FUME 1309-37-1 TWA: 5 mg/m3 TWA: 10 mg/m3 TWA: 5 mg/m3 TWA: 15 mg/m3 2500 mg/m3 AMORPHOUS SILICA 7631-86-9 -TWA: 6 mg/m3 3000 mg/m3 Appropriate engineering controls Engineering measures Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH''s Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Individual protection measures, such as personal protective equipment Eye/face protection Use chemical resistant splash type goggles. Skin and body protection Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Respiratory protection Use only with adequate ventilation. Do not breathe vapors, spray mist, or dust. Ensure fresh air entry during application and drying. If you experience eye watering, headache or dizziness or if air monitoring demonstrates vapor/mist or dust levels are above applicable limits, wear an appropriate, properly fitted respirator (NIOSH/MSHA approved) during and after application. Follow respirator manufacturer's directions for respirator use. General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. Avoid breathing dust created by cutting, sanding, or grinding. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state No information available ______________________________________________________________________________________________ Page 4 / 9 Property Values Odor Remarks No information available pH S244-00BGD ULTRA-TREAD BEIGE No data available Color No information available Revision Date 30-Nov-2015 Odor threshold No information available Appearance opaque ______________________________________________________________________________________________ Other Information Density 37.07 lbs/gal % 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions None under normal processing. Conditions to avoid Heat, flames and sparks. Incompatible materials Metals, Aluminum, Zinc, calcium Hazardous decomposition products Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide. Unidentified organic and inorganic compounds. Carbon dioxide. Hydrocarbons. 11. TOXICOLOGICAL INFORMATION Information on Likely Routes of Exposure Inhalation May cause central nervous system depression with nausea, headache, dizziness, vomiting, and incoordination. Eye contact Severely irritating to eyes. Skin contact Irritating to skin. Ingestion Harmful if swallowed. Component LD50 Oral LD50 Dermal LC50 Inhalation IRON OXIDE FUME 1309-37-1 > 10000 mg/kg ( Rat ) CHROMIC (III) OXIDE 1308-38-9 >5000 ______________________________________________________________________________________________ Page 5 / 9 S244-00BGD ULTRA-TREAD BEIGE Upper flammability limit NA No information availableMelting point / freezing point Lower flammability limit NA Flash point No data available No information available Vapor pressure No data available Vapor density No data available Revision Date 30-Nov-2015 Specific gravity 4.45 Evaporation rate g/cm3 Water solubility Insoluble in cold water No data available No data available Solubility in other solvents No data available Flammability (solid, gas) Partition coefficient: n-octanol/water No data available Autoignition temperature No information available No data available Boiling point / boiling range Decomposition temperature No data available Flammability Limit in Air Kinematic viscosity No data available Dynamic viscosity No data available No data available ______________________________________________________________________________________________ TITANIUM DIOXIDE (TOTAL DUST) 13463-67-7 > 10000 mg/kg ( Rat ) TITANIUM DIOXIDE (TOTAL DUST) 13463-67-7 > 10000 mg/kg ( Rat ) IRON OXIDE FUME 1309-37-1 > 10000 mg/kg ( Rat ) AMORPHOUS SILICA 7631-86-9 > 5000 mg/kg ( Rat )> 2000 mg/kg ( Rabbit )> 2.2 mg/L ( Rat ) 1 h Information on toxicological effects Symptoms Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Skin disorders. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Component ACGIH IARC NTP OSHA IRON OXIDE FUME 1309-37-1 Group 3 COBALT ALUMINATEBLUE SPINEL 1345-16-0 A3 Group 2B CHROMIC (III) OXIDE 1308-38-9 Group 3 TITANIUM DIOXIDE(TOTAL DUST) 13463-67-7 Group 2B X TITANIUM DIOXIDE (TOTAL DUST) 13463-67-7 Group 2B X IRON OXIDE FUME 1309-37-1 Group 3 AMORPHOUS SILICA 7631-86-9 Group 3 Reproductive effects No information available. STOT - single exposure No information available STOT - repeated exposure Causes damage to organs through prolonged or repeated exposure Target organ effects Eyes, respiratory system, Skin. Aspiration hazard No information available. The following values are calculated based on chapter 3.1 of the GHS document . 12. ECOLOGICAL INFORMATION Ecotoxicity Harmful to aquatic life with long lasting effects 601 % of the mixture consists of components(s) of unknown hazards to the aquatic environment Component Toxicity to algae Toxicity to fish Toxicity to daphnia AMORPHOUS SILICA 7631-86-9 440: 72 h Pseudokirchneriella subcapitata mg/L EC50 5000: 96 h Brachydanio rerio mg/L LC50 static 7600: 48 h Ceriodaphnia dubia mg/L EC50 Persistence and degradability No information available. Bioaccumulation No information available. Mobility in Environmental Media ______________________________________________________________________________________________ Page 6 / 9 Revision Date 30-Nov-2015S244-00BGD ULTRA-TREAD BEIGE ______________________________________________________________________________________________ Other Adverse Effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal Methods It must undergo special treatment, e.g. at suitable disposal site, to comply with local regulations. Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Component CAWAST COBALT ALUMINATE BLUE SPINEL 1345-16-0 Toxic CHROMIC (III) OXIDE 1308-38-9 Toxic Corrosive Ignitable 14. TRANSPORT INFORMATION DOT Proper Shipping Name Paint related material IATA Proper Shipping Name Not regulated Additional information Call TNEMEC Traffic Department - 816-474-3400 for additional information or other modes of Transportation. 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Complies IECSC Complies KECL Complies PICCS Complies AICS Complies TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61): Component HAPS Data COBALT ALUMINATE BLUE SPINEL CHROMIC (III) OXIDE United States of America ______________________________________________________________________________________________ Page 7 / 9 Revision Date 30-Nov-2015S244-00BGD ULTRA-TREAD BEIGE ______________________________________________________________________________________________ SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and and Title 40n of the Code of Federal Regulations, Part 372: Component SARA 313 - Threshold Values COBALT ALUMINATE BLUE SPINEL - 1345-16-0 0.1 CHROMIC (III) OXIDE - 1308-38-9 1.0 SARA 311/312 Hazardous Categorization Acute Health Hazard Yes Chronic Health Hazard Yes Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No Component CWA - ReportableQuantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - HazardousSubstances CHROMIC (III) OXIDE 1308-38-9 X CERCLA United States of America California Prop. 65 WARNING! This product contains a chemical known in the State of California to cause cancer Component California Prop. 65 TITANIUM DIOXIDE (TOTAL DUST) - 13463-67-7 Carcinogen TITANIUM DIOXIDE (TOTAL DUST) - 13463-67-7 Carcinogen California SCAQMD Rule 443 Does Not Contain Photochemically Reactive Solvent State Right-to-Know Component New Jersey Massachusetts Pennsylvania IRON OXIDE FUME 1309-37-1 X X X COBALT ALUMINATE BLUE SPINEL 1345-16-0 X X CHROMIC (III) OXIDE 1308-38-9 X X X TITANIUM DIOXIDE (TOTAL DUST) 13463-67-7 X X X TITANIUM DIOXIDE (TOTAL DUST) 13463-67-7 X X X IRON OXIDE FUME 1309-37-1 X X X AMORPHOUS SILICA 7631-86-9 X X X 16. OTHER INFORMATION ______________________________________________________________________________________________ Page 8 / 9 HMIS (Hazardous Material Information System) NFPA Health 2*Flammability 0 Reactivity 1 Health 2 Flammability 0 S244-00BGD ULTRA-TREAD BEIGE Instability 1 Physical hazard * Revision Date 30-Nov-2015 ______________________________________________________________________________________________ Prepared By Tnemec Regulatory Dept: 816-474-3400 Revision Date 30-Nov-2015 Revision Summary 9 5 6 7 10 8 11 14 15 1 Disclaimer For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. End of SDS ______________________________________________________________________________________________ Page 9 / 9 Revision Date 30-Nov-2015S244-00BGD ULTRA-TREAD BEIGE