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HomeMy WebLinkAboutSeries 246 SDSSafety Data Sheet Issue Date No data available Revision Date 12-Feb-2015 Revision Number 8 1. IDENTIFICATION Product identifier Product Code S244-0244A Product Name ULTRA-TREAD S244/S246 CLEAR Other means of identification Common Name SERIES 244/246, PART A Recommended use of the chemical and restrictions on use Recommended Use industrial paint. Uses advised against Consumer use, For professional use only. Not for residential use. Details of the supplier of the safety data sheet Emergency telephone number Company Phone Number Tnemec Regulatory Dept: 816-474-3400 24 Hour Emergency Phone Number 800-535-5053 (Infotrac) 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Skin sensitization Category 1 Germ cell mutagenicity Category 1B Carcinogenicity Category 1B Reproductive Toxicity Category 1B Label elements EMERGENCY OVERVIEW Manufacturer Address Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372 ______________________________________________________________________________________________ Danger Hazard statements May cause an allergic skin reaction May cause genetic defects May cause cancer May damage fertility or the unborn child Page 1 / 9 ______________________________________________________________________________________________ S244-0244A ULTRA-TREAD S244/S246 CLEAR Revision Date 12-Feb-2015 Precautionary Statements PreventionObtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Avoid breathing dust/fume/gas/mist/vapors/spray Contaminated work clothing should not be allowed out of the workplace Wear protective gloves Response IF exposed or concerned: Get medical advice/attention IF ON SKIN: Wash with plenty of soap and water If skin irritation or rash occurs: Get medical advice/attention Wash contaminated clothing before reuse Storage Store locked up Keep away from children Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Other information Causes mild skin irritation Very toxic to aquatic life with long lasting effects SEE SAFETY DATA SHEET Acute Toxicity 55.7018 % of the mixture consists of ingredient(s) of unknown toxicity. 3. COMPOSITION/INFORMATION ON INGREDIENTS Component CAS-No Weight-% WATER 7732-18-5 10 - 30% BUTYL BENZYL PHTHALATE 85-68-7 10 - 30% ALKYL GLYCIDYL ETHER 68609-97-2 1 - 10% DISTILLATES, PETROLEUM, HYDROREATED MIDDLE 64742-46-7 0.1 - 1% TRIETHANOLAMINE 102-71-6 0.1 - 1% 1-DODECENE 112-41-4 0.1 - 1% PETROLEUM SOLVENT (NAPTHA)64742-95-6 0.1 - 1% *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures General advice Show this safety data sheet to the doctor in attendance. ______________________________________________________________________________________________ Appearance opaque Page 2 / 9 Physical state liquid Odor Slight ______________________________________________________________________________________________ S244-0244A ULTRA-TREAD S244/S246 CLEAR Revision Date 12-Feb-2015 Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If symptoms persist, call a physician. Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If symptoms persist, call a physician. Inhalation Remove to fresh air. Oxygen or artificial respiration if needed. Ingestion If swallowed, do not induce vomiting. Get medical attention immediately. Self-protection of the first aider Use personal protective equipment. Avoid contact with eyes, skin and clothing. Most important symptoms and effects, both acute and delayed Notes to physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Water spray. Dry powder. Foam. Carbon dioxide (CO2). Unsuitable extinguishing media No information available. Specific hazards arising from the chemical Thermal decomposition can lead to release of irritating gases and vapours In the event of fire and/or explosion do not breathe fumes Hazardous combustion productsHazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide. Unidentified organic and inorganic compounds. Carbon dioxide (CO2). Hydrocarbons. Nitrogen oxides (NOx). Protective equipment and precautions for firefighters Use water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away from heat/sparks/open flames/hot surfaces. MAY CAUSE HEAT AND PRESSURE BUILD-UP IN CLOSED CONTAINERS. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Avoid contact with eyes, skin and clothing. Use personal protective equipment. Remove all sources of ignition. Environmental Precautions Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary sewer system. Methods and material for containment and cleaning up Methods for containment Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non-sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. ______________________________________________________________________________________________ Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminated absorbent, container and unused contents in accordance with local, state and federal regulations. 7. HANDLING AND STORAGE Page 3 / 9 ______________________________________________________________________________________________ S244-0244A ULTRA-TREAD S244/S246 CLEAR Revision Date 12-Feb-2015 Precautions for safe handling Handling Close container after each use. Avoid contact with eyes, skin and clothing. Do not eat, drink or smoke when using this product. If splashes are likely to occur, wear goggles. Wear protective gloves/clothing. Do not burn, or use a cutting torch on, the empty drum. When used in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling. Conditions for safe storage, including any incompatibilities Storage Keep container tightly closed in a dry and well-ventilated place. Keep out of the reach of children. Incompatible products Strong oxidizing agents. Strong bases. Strong acids. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure guidelines . Component ACGIH TLV OSHA PEL NIOSH IDLH TRIETHANOLAMINE 102-71-6 TWA: 5 mg/m3 - Appropriate engineering controls Engineering measures Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH''s Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Individual protection measures, such as personal protective equipment Eye/face protection Safety glasses with side-shields Skin and body protection Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Respiratory protection Use only with adequate ventilation. Do not breathe vapors, spray mist, or dust. Ensure fresh air entry during application and drying. If you experience eye watering, headache or dizziness or if air monitoring demonstrates vapor/mist or dust levels are above applicable limits, wear an appropriate, properly fitted respirator (NIOSH/MSHA approved) during and after application. Follow respirator manufacturer's directions for respirator use. General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. Avoid breathing dust created by cutting, sanding, or grinding. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state liquid Appearance opaque Odor Slight Color No information available Odor threshold No information available Property Values Remarks pH No data available Melting point / freezing point No data available Boiling point / boiling range 100 °C / 212.0 °F ______________________________________________________________________________________________ Flash point 60 °C / 140 °F Pensky Martens - Closed Cup Evaporation rate Page 4 / 9 No data available ______________________________________________________________________________________________ S244-0244A ULTRA-TREAD S244/S246 CLEAR Revision Date 12-Feb-2015 Other Information Density 8.44555 lbs/gal Volatile organic compounds (VOC) content .105 lbs/gal Total volatiles weight percent 29.8870 % Total volatiles volume percent 30.5123 % 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions None under normal processing. Conditions to avoid Heat, flames and sparks. Incompatible materials Strong oxidizing agents, Strong bases, Strong acids Hazardous decomposition products Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide. Unidentified organic and inorganic compounds. Carbon dioxide (CO2). Hydrocarbons. Nitrogen oxides (NOx). 11. TOXICOLOGICAL INFORMATION Information on Likely Routes of Exposure Inhalation May cause central nervous system depression with nausea, headache, dizziness, vomiting, and incoordination. Eye contact Irritating to eyes. Skin contact Irritating to skin. Ingestion Harmful if swallowed. Component LD50 Oral LD50 Dermal LC50 Inhalation WATER 7732-18-5 > 90 mL/kg ( Rat ) BUTYL BENZYL PHTHALATE 85-68-7 = 2330 mg/kg ( Rat )= 6700 mg/kg ( Rat )> 6.7 mg/L ( Rat ) 4 h Flammability (solid, gas)No information available Flammability Limit in Air No data available Upper flammability limit N/A Lower flammability limit N/A Vapor pressure No data available Vapor density No data available Specific gravity 1.01491 g/cm3 Water solubility Insoluble in cold water Solubility in other solvents No data available Partition coefficient: n-octanol/water No data available Autoignition temperature No data available Decomposition temperature No data available Kinematic viscosity ______________________________________________________________________________________________ No data available Dynamic viscosity 150 centipoises Page 5 / 9 No data available ______________________________________________________________________________________________ S244-0244A ULTRA-TREAD S244/S246 CLEAR Revision Date 12-Feb-2015 ALKYL GLYCIDYL ETHER 68609-97-2 = 17100 mg/kg ( Rat ) DISTILLATES, PETROLEUM, HYDROREATED MIDDLE 64742-46-7 = 7400 mg/kg ( Rat )> 2000 mg/kg ( Rabbit )= 4.6 mg/L ( Rat ) 4 h TRIETHANOLAMINE 102-71-6 = 4190 mg/kg ( Rat )> 16 mL/kg ( Rat ) > 20 mL/kg ( Rabbit ) 1-DODECENE 112-41-4 > 10000 mg/kg ( Rat )> 10000 mg/kg ( Rat ) PETROLEUM SOLVENT (NAPTHA) 64742-95-6 = 8400 mg/kg ( Rat )> 2000 mg/kg ( Rabbit )= 3400 ppm ( Rat ) 4 h Information on toxicological effects Symptoms Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Skin disorders. Delayed and immediate effects as well as chronic effects from short and long-term exposure Chronic Toxicity NOTICE: Reports have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Sensitization May cause sensitization of susceptible persons. Mutagenicity May cause genetic defects. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Component ACGIH IARC NTP OSHA BUTYL BENZYL PHTHALATE 85-68-7 Group 3 TRIETHANOLAMINE 102-71-6 Group 3 Reproductive effects May damage fertility or the unborn child. Developmental effects Developmental effects. STOT - single exposure No information available STOT - repeated exposure No information available Aspiration hazard Based on product level data, this product does not meet the requirement to be classified as an aspiration hazard. However, this product contains an ingredient that may cause aspiration if swallowed. Acute Toxicity 55.7018 % of the mixture consists of ingredient(s) of unknown toxicity. 12. ECOLOGICAL INFORMATION Ecotoxicity Very toxic to aquatic life with long lasting effects 58.2874 % of the mixture consists of components(s) of unknown hazards to the aquatic environment Component Toxicity to algae Toxicity to fish Toxicity to daphnia BUTYL BENZYL PHTHALATE 85-68-7 0.02 - 0.25: 96 h Pseudokirchneriella subcapitata mg/L EC50 0.2 - 28.2: 72 h Pseudokirchneriella subcapitata mg/L EC50 ______________________________________________________________________________________________ 0.82: 96 h Oncorhynchus mykiss mg/L LC50 flow-through 1.0 - 10.0: 96 h Lepomis macrochirus mg/L LC50 static 1.39 - 3.88: 96 h Pimephales promelas mg/L LC50flow-through 1.0 - 10.0: 96 h Oncorhynchus mykiss mg/L LC50 static 0.78: 96 h Pimephales promelas mg/L LC50 static 0.97: 48 h Daphnia magna mg/L EC50 1.28: 48 h Daphnia magna mg/L EC50 semi-static 0.9 - 1.1: 48 h Daphnia magna mg/L EC50 Static 0.76: 48 h Daphnia magna mg/LEC50 Flow through DISTILLATES, PETROLEUM, HYDROREATED MIDDLE 64742-46-7 Page 6 / 9 10000: 96 h Pimephales promelas mg/L LC50 static 35: 96 h Pimephales promelas mg/L LC50 flow-through ______________________________________________________________________________________________ S244-0244A ULTRA-TREAD S244/S246 CLEAR Revision Date 12-Feb-2015 TRIETHANOLAMINE 102-71-6 216: 72 h Desmodesmus subspicatus mg/L EC50 169: 96 h Desmodesmus subspicatus mg/L EC50 10600 - 13000: 96 h Pimephales promelas mg/L LC50 flow-through 1000: 96 h Pimephales promelas mg/L LC50 static 450 - 1000: 96 h Lepomis macrochirus mg/L LC50 static 1386: 24 h Daphnia magna mg/L EC50 PETROLEUM SOLVENT (NAPTHA) 64742-95-6 9.22: 96 h Oncorhynchus mykiss mg/L LC50 6.14: 48 h Daphnia magna mg/L EC50 Persistence and degradability No information available. Bioaccumulation No information available. Mobility in Environmental Media Component log Pow BUTYL BENZYL PHTHALATE 85-68-7 3.57 - 4.91 TRIETHANOLAMINE 102-71-6 -2.53 Other Adverse Effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal Methods Keep container tightly closed. If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminated absorbent, container and unused contents in accordance with local, state and federal regulations. Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Component RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes BUTYL BENZYL PHTHALATE 85-68-7 Included in waste stream: F039 14. TRANSPORT INFORMATION DOT Proper Shipping Name paint,water base freezable Not regulated IATA UN/ID no.1263 Proper Shipping Name paint Hazard Class 3 Packing Group III ERG Code 366 ______________________________________________________________________________________________ Additional information Call TNEMEC Traffic Department - 816-474-3400 for additional information or other modes of Transportation. 15. REGULATORY INFORMATION Page 7 / 9 International Inventories ______________________________________________________________________________________________ S244-0244A ULTRA-TREAD S244/S246 CLEAR Revision Date 12-Feb-2015 TSCA Complies DSL/NDSL Complies EINECS/ELINCS Does not comply ENCS Does not comply IECSC Complies KECL Does not comply PICCS Does not comply AICS Complies TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances United States of America SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and and Title 40n of the Code of Federal Regulations, Part 372. SARA 311/312 Hazardous Categorization Acute Health Hazard Yes Chronic Health Hazard Yes Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No Component CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances BUTYL BENZYL PHTHALATE 85-68-7 X X CERCLA Component Hazardous Substances RQs CERCLA EHS RQs RQ BUTYL BENZYL PHTHALATE 85-68-7 100 lb RQ 100 lb final RQ RQ 45.4 kg final RQ United States of America California Prop. 65 WARNING! This product contains a chemical known in the State of California to cause cancer Component California Prop. 65 BUTYL BENZYL PHTHALATE - 85-68-7 Developmental California SCAQMD Rule 443 Contains Photochemically Reactive Solvent State Right-to-Know Component New Jersey Massachusetts Pennsylvania WATER 7732-18-5 ______________________________________________________________________________________________ X BUTYL BENZYL PHTHALATE 85-68-7 X Page 8 / 9 X X ______________________________________________________________________________________________ S244-0244A ULTRA-TREAD S244/S246 CLEAR Revision Date 12-Feb-2015 TRIETHANOLAMINE 102-71-6 X X X 16. OTHER INFORMATION Prepared By Tnemec Regulatory Dept: 816-474-3400 Revision Date 12-Feb-2015 Revision Summary 9 4 5 7 10 11 14 15 Disclaimer For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. End of MSDS NFPA Health 2 Flammability 1 Instability 1 ______________________________________________________________________________________________ Physical hazard * HMIS (Hazardous Material Information System) Health 2*Flammability 1 Page 9 / 9 Reactivity 1 Safety Data Sheet Issue Date No data available Revision Date 12-Feb-2015 Revision Number 7 1. IDENTIFICATION Product identifier Product Code S244-0244B Product Name ULTRA-TREAD S244/S246 CONVERTE Other means of identification Common Name SERIES 244/246 PART B Recommended use of the chemical and restrictions on use Recommended Use industrial paint. Uses advised against Consumer use, For professional use only. Not for residential use. Details of the supplier of the safety data sheet Emergency telephone number Company Phone Number Tnemec Regulatory Dept: 816-474-3400 24 Hour Emergency Phone Number 800-535-5053 (Infotrac) 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Acute toxicity - Inhalation (Vapors)Category 4 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2 Respiratory sensitization Category 1 Skin sensitization Category 1 Carcinogenicity Category 2 Specific target organ toxicity (single exposure)Category 3 Specific target organ toxicity (repeated exposure)Category 2 Label elements EMERGENCY OVERVIEW ______________________________________________________________________________________________ Manufacturer Address Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372 Danger Page 1 / 9 Hazard statements Harmful if inhaled Causes skin irritation Causes serious eye irritation May cause allergy or asthma symptoms or breathing difficulties if inhaled May cause an allergic skin reaction Suspected of causing cancer May cause respiratory irritation May cause damage to organs through prolonged or repeated exposure ______________________________________________________________________________________________ S244-0244B ULTRA-TREAD S244/S246 CONVERTE Revision Date 12-Feb-2015 Precautionary Statements Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Use only outdoors or in a well-ventilated area Wash face, hands and any exposed skin thoroughly after handling In case of inadequate ventilation wear respiratory protection Contaminated work clothing should not be allowed out of the workplace Wear protective gloves Do not breathe dust/fume/gas/mist/vapors/spray Response IF exposed or concerned: Get medical advice/attention IF ON SKIN: Wash with plenty of soap and water Take off contaminated clothing and wash before reuse If skin irritation or rash occurs: Get medical advice/attention IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician Storage Store locked up Store in a well-ventilated place. Keep container tightly closed Keep away from children Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Other information Acute Toxicity 0 % of the mixture consists of ingredient(s) of unknown toxicity. 3. COMPOSITION/INFORMATION ON INGREDIENTS Component CAS-No Weight-% DIPHENYLMETHANE DIISOCYANATE (MDI) POLYMER 9016-87-9 30 - 60% DIPHENYLMETHANE DIISOCYANATE (VOLATILE MONOMER) 101-68-8 30 - 60% DIPHENYLMETHANE DIISOCYANATE (MDI) POLYMER 5873-54-1 10 - 30% 2,2'-DIPHENYLMETHANE DIISOCYANATE 2536-05-2 1 - 10% *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES ______________________________________________________________________________________________ Appearance clear Page 2 / 9 Physical state liquid Odor Slight ______________________________________________________________________________________________ S244-0244B ULTRA-TREAD S244/S246 CONVERTE Revision Date 12-Feb-2015 Description of first aid measures General advice Show this safety data sheet to the doctor in attendance. Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If symptoms persist, call a physician. Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If symptoms persist, call a physician. Inhalation Remove to fresh air. Oxygen or artificial respiration if needed. Ingestion If swallowed, do not induce vomiting. Get medical attention immediately. Self-protection of the first aider Avoid breathing vapors or mists. Most important symptoms and effects, both acute and delayed Notes to physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing mediaCarbon dioxide (CO2). Dry chemical. Dry powder. Unsuitable extinguishing media Water. Specific hazards arising from the chemical Thermal decomposition can lead to release of irritating gases and vapours In the event of fire and/or explosion do not breathe fumes Hazardous combustion productsHazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide. Unidentified organic and inorganic compounds. Carbon dioxide (CO2). Hydrocarbons. Nitrogen oxides (NOx). Isocyanates. Protective equipment and precautions for firefighters Use water spray to cool unopened containers. In the event of fire, wear self-contained breathing apparatus. Keep away from heat/sparks/open flames/hot surfaces. MAY CAUSE HEAT AND PRESSURE BUILD-UP IN CLOSED CONTAINERS. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Avoid contact with eyes, skin and clothing. Use personal protective equipment. Remove all sources of ignition. Ensure adequate ventilation. Environmental Precautions Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary sewer system. ______________________________________________________________________________________________ Methods and material for containment and cleaning up Methods for containment Page 3 / 9 Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non-sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. ______________________________________________________________________________________________ S244-0244B ULTRA-TREAD S244/S246 CONVERTE Revision Date 12-Feb-2015 Methods for cleaning up If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminated absorbent, container and unused contents in accordance with local, state and federal regulations. 7. HANDLING AND STORAGE Precautions for safe handling Handling Use only with adequate ventilation.Avoid contact with eyes, skin and clothing. Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Do not eat, drink or smoke when using this product. When used in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling. Conditions for safe storage, including any incompatibilities Storage Keep container tightly closed in a dry and well-ventilated place. Keep out of the reach of children. Incompatible products Water. Amines. Strong bases. Alcohols. copper. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure guidelines . Component ACGIH TLV OSHA PEL NIOSH IDLH DIPHENYLMETHANE DIISOCYANATE (VOLATILE MONOMER) 101-68-8 TWA: 0.005 ppm Ceiling: 0.02 ppm Ceiling: 0.2 mg/m3 75 mg/m3 NIOSH IDLH: Immediately Dangerous to Life or Health Appropriate engineering controls Engineering measures Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH''s Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Individual protection measures, such as personal protective equipment Eye/face protection Use chemical resistant splash type goggles. If splashes are likely to occur, wear face-shield. Skin and body protection Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Respiratory protection Use only with adequate ventilation. Do not breathe vapors, spray mist, or dust. Ensure fresh air entry during application and drying. If you experience eye watering, headache or dizziness or if air monitoring demonstrates vapor/mist or dust levels are above applicable limits, wear an appropriate, properly fitted respirator (NIOSH/MSHA approved) during and after application. Follow respirator manufacturer's directions for respirator use. General hygiene considerations ______________________________________________________________________________________________ Handle in accordance with good industrial hygiene and safety practice. Avoid breathing dust created by cutting, sanding, or grinding. 9. PHYSICAL AND CHEMICAL PROPERTIES Page 4 / 9 Information on basic physical and chemical properties ______________________________________________________________________________________________ S244-0244B ULTRA-TREAD S244/S246 CONVERTE Revision Date 12-Feb-2015 Physical state liquid Other Information Density 10.3293 lbs/gal Volatile organic compounds (VOC) content 4.33831 lbs/gal Total volatiles weight percent 42 % Total volatiles volume percent 36.15 % 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions None under normal processing. Conditions to avoid Heat, flames and sparks. Incompatible materials Water, Amines, Strong bases, Alcohols, copper Hazardous decomposition products Hazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide. Unidentified organic and inorganic compounds. Carbon dioxide (CO2). Hydrocarbons. Nitrogen oxides (NOx). Isocyanates. 11. TOXICOLOGICAL INFORMATION Information on Likely Routes of Exposure Appearance clear Odor Slight Color No information available Odor threshold No information available Property Values Remarks pH No data available Melting point / freezing point No data available Boiling point / boiling range 72 °C / 162 °F Flash point No information available Evaporation rate No data available Flammability (solid, gas)No information available Flammability Limit in Air No data available Upper flammability limit N/A Lower flammability limit N/A Vapor pressure No data available Vapor density No data available Specific gravity 1.23853 g/cm3 Water solubility Insoluble in cold water Solubility in other solvents No data available Partition coefficient: n-octanol/water No data available Autoignition temperature No data available Decomposition temperature No data available Kinematic viscosity ______________________________________________________________________________________________ No data available Dynamic viscosity 145 mPa s Page 5 / 9 No data available ______________________________________________________________________________________________ S244-0244B ULTRA-TREAD S244/S246 CONVERTE Revision Date 12-Feb-2015 Inhalation Contains isocyanate monomer. If subject to spray application, engineering and administrative controls must be instituted to maintain an exposure level below .005ppm. If these controls are not adequate, the use of an air-supplied respirator is mandatory. May cause sensitization of susceptible persons. Eye contact Severely irritating to eyes. Skin contact Irritating to skin. May cause sensitization of susceptible persons. Ingestion Harmful if swallowed. Component LD50 Oral LD50 Dermal LC50 Inhalation DIPHENYLMETHANE DIISOCYANATE (MDI) POLYMER 9016-87-9 = 49 g/kg ( Rat )> 9400 mg/kg ( Rabbit )= 490 mg/m3 ( Rat ) 4 h DIPHENYLMETHANE DIISOCYANATE (VOLATILE MONOMER) 101-68-8 = 31600 mg/kg ( Rat ) = 9200 mg/kg ( Rat ) = 369 mg/m3 ( Rat ) 4 h Information on toxicological effects Symptoms Respiratory disorders. Skin disorders. Delayed and immediate effects as well as chronic effects from short and long-term exposure Chronic Toxicity Avoid repeated exposure. Contains isocyanates. May produce an allergic reaction. Sensitization May cause sensitization of susceptible persons. Mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Component ACGIH IARC NTP OSHA DIPHENYLMETHANE DIISOCYANATE (MDI) POLYMER 9016-87-9 Group 3 DIPHENYLMETHANE DIISOCYANATE (VOLATILE MONOMER) 101-68-8 Group 3 Reproductive effects No information available. STOT - single exposure Eyes, Skin, Respiratory system STOT - repeated exposure Causes damage to organs through prolonged or repeated exposure Target organ effects Eyes, respiratory system. Aspiration hazard Based on product level data, this product does not meet the requirement to be classified as an aspiration hazard. However, this product contains an ingredient that may cause aspiration if swallowed. Acute Toxicity 0 % of the mixture consists of ingredient(s) of unknown toxicity. 12. ECOLOGICAL INFORMATION Ecotoxicity 48 % of the mixture consists of components(s) of unknown hazards to the aquatic environment Persistence and degradability No information available. ______________________________________________________________________________________________ BioaccumulationNo information available. Mobility in Environmental Media Page 6 / 9 ______________________________________________________________________________________________ S244-0244B ULTRA-TREAD S244/S246 CONVERTE Revision Date 12-Feb-2015 Other Adverse Effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal Methods Keep container tightly closed. If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminated absorbent, container and unused contents in accordance with local, state and federal regulations. Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. 14. TRANSPORT INFORMATION DOT Proper Shipping Name paint in oil Not regulated IATA Proper Shipping Name Not regulated Additional information Call TNEMEC Traffic Department - 816-474-3400 for additional information or other modes of Transportation. 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Does not comply ENCS Complies IECSC Complies KECL Complies PICCS Complies AICS Complies TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61): Component HAPS Data DIPHENYLMETHANE DIISOCYANATE (VOLATILE MONOMER) United States of America ______________________________________________________________________________________________ SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and and Title 40n of the Code of Federal Regulations, Part 372: Component SARA 313 - Threshold Values Page 7 / 9 DIPHENYLMETHANE DIISOCYANATE (MDI) POLYMER - 9016-87-9 1.0 ______________________________________________________________________________________________ S244-0244B ULTRA-TREAD S244/S246 CONVERTE Revision Date 12-Feb-2015 DIPHENYLMETHANE DIISOCYANATE (VOLATILE MONOMER) - 101-68-8 1.0 DIPHENYLMETHANE DIISOCYANATE (MDI) POLYMER - 5873-54-1 1.0 2,2'-DIPHENYLMETHANE DIISOCYANATE - 2536-05-2 1.0 SARA 311/312 Hazardous Categorization Acute Health Hazard Yes Chronic Health Hazard Yes Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No CERCLA Component Hazardous Substances RQs CERCLA EHS RQs RQ DIPHENYLMETHANE DIISOCYANATE (VOLATILE MONOMER) 101-68-8 5000 lb RQ 5000 lb final RQ RQ 2270 kg final RQ United States of America California Prop. 65 WARNING! This product contains a chemical known in the State of California to cause cancer California SCAQMD Rule 443Contains Photochemically Reactive Solvent State Right-to-Know Component New Jersey Massachusetts Pennsylvania DIPHENYLMETHANE DIISOCYANATE (MDI) POLYMER 9016-87-9 X DIPHENYLMETHANE DIISOCYANATE (VOLATILE MONOMER) 101-68-8 X X X DIPHENYLMETHANE DIISOCYANATE (MDI) POLYMER 5873-54-1 X 2,2'-DIPHENYLMETHANE DIISOCYANATE 2536-05-2 X 16. OTHER INFORMATION Prepared By Tnemec Regulatory Dept: 816-474-3400 Revision Date 12-Feb-2015 Revision Summary 9 4 5 6 7 10 8 11 14 NFPA Health 3 Flammability 1 Instability 1 ______________________________________________________________________________________________ Physical hazard * HMIS (Hazardous Material Information System) Health 3*Flammability 1 Page 8 / 9 Reactivity 1 ______________________________________________________________________________________________ S244-0244B ULTRA-TREAD S244/S246 CONVERTE Revision Date 12-Feb-2015 Disclaimer For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. ______________________________________________________________________________________________ End of MSDS Page 9 / 9 Safety Data Sheet Issue Date No data available Revision Date 16-Feb-2015 Revision Number 6 1. IDENTIFICATION Product identifier Product Code S246-0246C Product Name ULTRA-TREAD GLAZE AGGREGATE Other means of identification Common Name SERIES 246 PART C Recommended use of the chemical and restrictions on use Recommended Use industrial paint. Uses advised against Consumer use, For professional use only. Not for residential use. Details of the supplier of the safety data sheet Emergency telephone number Company Phone Number Tnemec Regulatory Dept: 816-474-3400 24 Hour Emergency Phone Number 800-535-5053 (Infotrac) 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 1 Skin sensitization Category 1 Carcinogenicity Category 1A Specific target organ toxicity (single exposure)Category 3 Specific target organ toxicity (repeated exposure)Category 1 Label elements EMERGENCY OVERVIEW ______________________________________________________________________________________________ Manufacturer Address Tnemec Company, Inc. 6800 Corporate Drive, Kansas City, MO 64120-1372 Danger Page 1 / 9 Hazard statements Causes skin irritation Causes serious eye damage May cause an allergic skin reaction May cause cancer May cause respiratory irritation Causes damage to organs through prolonged or repeated exposure ______________________________________________________________________________________________ S246-0246C ULTRA-TREAD GLAZE AGGREGATE Revision Date 16-Feb-2015 Precautionary Statements Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Contaminated work clothing should not be allowed out of the workplace Wear protective gloves Use only outdoors or in a well-ventilated area Do not breathe dust/fume/gas/mist/vapors/spray Do not eat, drink or smoke when using this product Response IF exposed or concerned: Get medical advice/attention IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a POISON CENTER or doctor/physician IF ON SKIN: Wash with plenty of soap and water Take off contaminated clothing and wash before reuse If skin irritation or rash occurs: Get medical advice/attention IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Storage Store locked up Store in a well-ventilated place. Keep container tightly closed Keep away from children Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Other information May be harmful if swallowed Harmful to aquatic life with long lasting effects Cancer hazard. Contains crystalline silica which can cause cancer. (Risk of cancer depends on duration and level of exposure). Respirable crystalline silica (quartz) can cause silicosis, a fibrosis (scarring) of the lungs Exposure of sufficient duration to wet cement, or to dry cement on moist areas of the body, can cause serious, potentially irreversible tissue (skin, eye, respiratory tract) damage due to chemical (caustic) burns, including third degree burns SEE SAFETY DATA SHEET Acute Toxicity 46.7618 % of the mixture consists of ingredient(s) of unknown toxicity. 3. COMPOSITION/INFORMATION ON INGREDIENTS Component CAS-No Weight-% CALCIUM SILICATES AND ALUMINATES 65997-15-1 60 - 100% IRON OXIDE FUME 1309-37-1 10 - 30% CALCIUM HYDROXIDE 1305-62-0 1 - 10% GYPSUM 13397-24-5 1 - 10% ______________________________________________________________________________________________ Appearance off-white Page 2 / 9 Physical state powder Odor No information available ______________________________________________________________________________________________ S246-0246C ULTRA-TREAD GLAZE AGGREGATE Revision Date 16-Feb-2015 MAGNESIUM OXIDE 1309-48-4 1 - 10% LIMESTONE 1317-65-3 1 - 10% CRYSTALLINE SILICA (QUARTZ)14808-60-7 1 - 10% CALCIUM OXIDE 1305-78-8 1 - 10% *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures General advice Show this safety data sheet to the doctor in attendance. Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If symptoms persist, call a physician. Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. If symptoms persist, call a physician. Inhalation Remove to fresh air. Oxygen or artificial respiration if needed. Ingestion If swallowed, do not induce vomiting. Get medical attention immediately. Self-protection of the first aider Use personal protective equipment. Avoid contact with eyes, skin and clothing. Most important symptoms and effects, both acute and delayed Notes to physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2). Dry powder. Dry chemical. Foam. Unsuitable extinguishing media No information available. Specific hazards arising from the chemical Thermal decomposition can lead to release of irritating gases and vapours In the event of fire and/or explosion do not breathe fumes Hazardous combustion productsHazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide. Unidentified organic and inorganic compounds. Carbon dioxide (CO2). Hydrocarbons. Nitrogen oxides (NOx). Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Avoid contact with eyes, skin and clothing. Use personal protective equipment. Remove all sources of ignition. ______________________________________________________________________________________________ Environmental Precautions Environmental precautions Prevent further leakage or spillage if safe to do so. Do not flush into surface water or sanitary sewer system. Page 3 / 9 Methods and material for containment and cleaning up ______________________________________________________________________________________________ S246-0246C ULTRA-TREAD GLAZE AGGREGATE Revision Date 16-Feb-2015 Methods for containment Remove all sources of ignition. Spills may be collected with inert, absorbent material for proper disposal. Use non-sparking tools, protective gloves, goggles and clothing, adequate ventilation, avoid the breathing of vapors and use respiratory protective devices. Transfer absorbent material to suitable containers for proper disposal. Methods for cleaning up Shovel or sweep up. 7. HANDLING AND STORAGE Precautions for safe handling Handling Close container after each use. Avoid contact with eyes, skin and clothing. Do not eat, drink or smoke when using this product. Tightly fitting safety goggles. Wear protective gloves/clothing. When used in a mixture, read the labels and safety data sheets of all components. Wash thoroughly after handling. Conditions for safe storage, including any incompatibilities Storage Keep container tightly closed in a dry and well-ventilated place. Keep out of the reach of children. Incompatible products Acids. Ammonia. Aluminum. Oxides of phosphorous. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure guidelines . Component ACGIH TLV OSHA PEL NIOSH IDLH CALCIUM SILICATES AND ALUMINATES 65997-15-1 TWA: 1 mg/m3 TWA: 10 mg/m3 TWA: 5 mg/m3 TWA: 15 mg/m3 5000 mg/m3 IRON OXIDE FUME 1309-37-1 TWA: 5 mg/m3 TWA: 10 mg/m3 TWA: 5 mg/m3 TWA: 15 mg/m3 2500 mg/m3 CALCIUM HYDROXIDE 1305-62-0 TWA: 5 mg/m3 TWA: 5 mg/m3 TWA: 15 mg/m3 GYPSUM 13397-24-5 TWA: 10 mg/m3 TWA: 15 mg/m3 TWA: 5 mg/m3 MAGNESIUM OXIDE 1309-48-4 TWA: 10 mg/m3 TWA: 10 mg/m3 TWA: 15 mg/m3 750 mg/m3 LIMESTONE 1317-65-3 -TWA: 15 mg/m3 TWA: 5 mg/m3 CRYSTALLINE SILICA (QUARTZ) 14808-60-7 TWA: 0.025 mg/m3 TWA: 0.1 mg/m3 50 mg/m3 CALCIUM OXIDE 1305-78-8 ______________________________________________________________________________________________ TWA: 2 mg/m3 TWA: 5 mg/m3 25 mg/m3 NIOSH IDLH: Immediately Dangerous to Life or Health Page 4 / 9 Appropriate engineering controls ______________________________________________________________________________________________ S246-0246C ULTRA-TREAD GLAZE AGGREGATE Revision Date 16-Feb-2015 Engineering measures Sufficient ventilation, in volume and pattern, should be provided through both local and general exhaust to keep the air contaminant concentration below current applicable OSHA Permissible Exposure Limits (PEL) and ACGIH''s Threshold Limit Values (TLV). Appropriate ventilation should be employed to remove hazardous decomposition products formed during welding or flame cutting operations of surfaces coated with this product. Individual protection measures, such as personal protective equipment Eye/face protection Use chemical resistant splash type goggles. If splashes are likely to occur, wear face-shield. Skin and body protection Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Respiratory protection Use only with adequate ventilation. Do not breathe vapors, spray mist, or dust. Ensure fresh air entry during application and drying. If you experience eye watering, headache or dizziness or if air monitoring demonstrates vapor/mist or dust levels are above applicable limits, wear an appropriate, properly fitted respirator (NIOSH/MSHA approved) during and after application. Follow respirator manufacturer's directions for respirator use. General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. Avoid breathing dust created by cutting, sanding, or grinding. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state powder Other Information Density 25.37183 lbs/gal Volatile organic compounds (VOC) content .000 lbs/gal Total volatiles weight percent .0000 % Total volatiles volume percent .0000 % 10. STABILITY AND REACTIVITY Appearance off-white Odor No information available Color No information available Odor threshold No information available Property Values Remarks pH No data available Melting point / freezing point No data available Boiling point / boiling range No information available Flash point No information available Evaporation rate No data available Flammability (solid, gas)No information available Flammability Limit in Air No data available Upper flammability limit N/A Lower flammability limit N/A Vapor pressure No data available Vapor density No data available Specific gravity 3.04895 g/cm3 Water solubility Insoluble in cold water Solubility in other solvents No data available Partition coefficient: n-octanol/water No data available Autoignition temperature No data available Decomposition temperature No data available ______________________________________________________________________________________________ Kinematic viscosity No data available Dynamic viscosity Page 5 / 9 No data available ______________________________________________________________________________________________ S246-0246C ULTRA-TREAD GLAZE AGGREGATE Revision Date 16-Feb-2015 Reactivity Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions None under normal processing. Conditions to avoid Heat, flames and sparks. Incompatible materials Acids, Ammonia, Aluminum, Oxides of phosphorous Hazardous decomposition productsHazardous combustion products may include: A complex mixture of airborne solid and liquid particulates and gases (smoke). Carbon monoxide. Unidentified organic and inorganic compounds. Carbon dioxide (CO2). Hydrocarbons. Nitrogen oxides (NOx). 11. TOXICOLOGICAL INFORMATION Information on Likely Routes of Exposure Inhalation May cause central nervous system depression with nausea, headache, dizziness, vomiting, and incoordination. Eye contact Severely irritating to eyes. May cause irreversible damage to eyes. Skin contact Contact causes severe skin irritation and possible burns. Repeated or prolonged skin contact may cause allergic reactions with susceptible persons. Ingestion Harmful if swallowed. Component LD50 Oral LD50 Dermal LC50 Inhalation IRON OXIDE FUME 1309-37-1 > 10000 mg/kg ( Rat ) CALCIUM HYDROXIDE 1305-62-0 = 7340 mg/kg ( Rat ) CRYSTALLINE SILICA (QUARTZ) 14808-60-7 = 500 mg/kg ( Rat ) CALCIUM OXIDE 1305-78-8 = 500 mg/kg ( Rat ) Information on toxicological effects Symptoms Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting. Skin disorders. Delayed and immediate effects as well as chronic effects from short and long-term exposure Chronic Toxicity Cancer hazard. Contains crystalline silica which can cause cancer. (Risk of cancer depends on duration and level of exposure). Sensitization May cause sensitization of susceptible persons. Mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Component ACGIH IARC NTP OSHA IRON OXIDE FUME 1309-37-1 Group 3 CRYSTALLINE SILICA (QUARTZ) 14808-60-7 A2 Group 1 Known ______________________________________________________________________________________________ X Reproductive effects No information available. STOT - single exposure Page 6 / 9 Skin, Eyes, Lungs No data available ______________________________________________________________________________________________ S246-0246C ULTRA-TREAD GLAZE AGGREGATE Revision Date 16-Feb-2015 STOT - repeated exposure Causes damage to organs through prolonged or repeated exposure Target organ effects Eyes, respiratory system, Skin, Lungs. Aspiration hazard No information available. Acute Toxicity 46.7618 % of the mixture consists of ingredient(s) of unknown toxicity. 12. ECOLOGICAL INFORMATION Ecotoxicity Harmful to aquatic life with long lasting effects 77.9221 % of the mixture consists of components(s) of unknown hazards to the aquatic environment Component Toxicity to algae Toxicity to fish Toxicity to daphnia CALCIUM HYDROXIDE 1305-62-0 160: 96 h Gambusia affinis mg/L LC50 static CALCIUM OXIDE 1305-78-8 1070: 96 h Cyprinus carpio mg/L LC50 static Persistence and degradability No information available. Bioaccumulation No information available. Mobility in Environmental Media Other Adverse Effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal Methods Keep container tightly closed. If spilled, contain spilled material and remove with inert absorbent. Dispose of contaminated absorbent, container and unused contents in accordance with local, state and federal regulations. Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. California Hazardous Waste Status This product contains one or more substances that are listed with the State of California as a hazardous waste Component CAWAST CALCIUM SILICATES AND ALUMINATES 65997-15-1 Special CALCIUM HYDROXIDE 1305-62-0 Corrosive CALCIUM OXIDE 1305-78-8 Corrosive 14. TRANSPORT INFORMATION DOT Proper Shipping Name SILICA, N.O.I.-20-P.C.F., GREATER (ITEM 176370, SUB 3) ______________________________________________________________________________________________ IATA Page 7 / 9 Proper Shipping Name Not regulated ______________________________________________________________________________________________ S246-0246C ULTRA-TREAD GLAZE AGGREGATE Revision Date 16-Feb-2015 Additional information Call TNEMEC Traffic Department - 816-474-3400 for additional information or other modes of Transportation. 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Does not comply ENCS Does not comply IECSC Complies KECL Does not comply PICCS Does not comply AICS Does not comply TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances United States of America SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and and Title 40n of the Code of Federal Regulations, Part 372. SARA 311/312 Hazardous Categorization Acute Health Hazard Yes Chronic Health Hazard Yes Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No CERCLA United States of America California Prop. 65 WARNING! This product contains a chemical known in the State of California to cause cancer Component California Prop. 65 CRYSTALLINE SILICA (QUARTZ) - 14808-60-7 Carcinogen California SCAQMD Rule 443 Does Not Contain Photochemically Reactive Solvent State Right-to-Know Component New Jersey ______________________________________________________________________________________________ Massachusetts Pennsylvania CALCIUM SILICATES AND ALUMINATES 65997-15-1 X Page 8 / 9 X X ______________________________________________________________________________________________ S246-0246C ULTRA-TREAD GLAZE AGGREGATE Revision Date 16-Feb-2015 IRON OXIDE FUME 1309-37-1 X X X CALCIUM HYDROXIDE 1305-62-0 X X X GYPSUM 13397-24-5 X X MAGNESIUM OXIDE 1309-48-4 X X X LIMESTONE 1317-65-3 X X X CRYSTALLINE SILICA (QUARTZ) 14808-60-7 X X X CALCIUM OXIDE 1305-78-8 X X X 16. OTHER INFORMATION Prepared By Tnemec Regulatory Dept: 816-474-3400 Revision Date 16-Feb-2015 Revision Summary 9 4 5 7 10 8 11 14 15 Disclaimer For specific information regarding occupational safety and health standards, please refer to the Code of Federal Regulations, Title 29, Part 1910. To the best of our knowledge, the information contained herein is accurate. However, neither the Tnemec Company or any of its subsidiaries assume any liability whatsoever for the accuracy of completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown health hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards which exist. End of MSDS NFPA Health 2 Flammability 1 Instability 0 ______________________________________________________________________________________________ Physical hazard * HMIS (Hazardous Material Information System) Health 2*Flammability 1 Page 9 / 9 Reactivity 0